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The Formation of Solid Derivs. of Aldehydes I

日期:2016-03-21

摘要:1,2-Bis(p-methoxybenzylamino)ethane has been found to be a very satisfactory reagent for the characterization of aldehydes. Acetone is the only ketone found to react with this diamine. Twenty-tWe new solid derivatives of 1 ,2-bis(p-methoxybenzy1amino)ethane have been prepared. These compounds are 2-substituted-1 ,3-bis(p-methoxyhenzyl)tetrahydroimidazoles. 1 ,2-Bis(pmethoxybenzy1amino)ethane dihydrochloride has been synthesized by a new method. The aldehydes were regenerated in approximately quantitative yields by treatment of the tetrahydroimidazole with dilute hydrochloric acid.

作者:J.H.Billman, J.Y.Chen Ho et al

来源(出处):J. Org. Chem. 1952, 17, 1375

出版日期:1952年

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The Formation of Solid Derivs. of Aldehydes I

日期:2016-03-21

摘要:1,2-Bis(p-methoxybenzylamino)ethane has been found to be a very satisfactory reagent for the characterization of aldehydes. Acetone is the only ketone found to react with this diamine. Twenty-tWe new solid derivatives of 1 ,2-bis(p-methoxybenzy1amino)ethane have been prepared. These compounds are 2-substituted-1 ,3-bis(p-methoxyhenzyl)tetrahydroimidazoles. 1 ,2-Bis(pmethoxybenzy1amino)ethane dihydrochloride has been synthesized by a new method. The aldehydes were regenerated in approximately quantitative yields by treatment of the tetrahydroimidazole with dilute hydrochloric acid.

作者:J.H.Billman, J.Y.Chen Ho et al

来源(出处):J. Org. Chem. 1952, 17, 1375

出版日期:1952年