研究论文

[1]H. R. Davis, S. H. -K. Chiang， Dehalogenation of Organic

Compounds in the Presence of a Detergent, U. S. Pat. 2744798

(1956).

[2]S. H. -K. Jiang, The Addition Reactions of Sulfur Trioxide to

Carbon-Carbon Double Bonds. The Addition Products of Sulfur

Trioxide and Some Perfluoroolefins, Acta Chimica Sinica 1957,

23,330.

[3]S. H. -K. Jiang, Some Derivatives of Dihydronaphthalene and the

Proof of Their Structures. Acta Chimica Sinica 1957,23,351.

[4]H. J. Dauben, Jr. , S. H. -K. Jiang, V. R. Ben, Bicyclo (3,3,0)-

Octa-3,7-Dien-2,6-Dione. Acta Chimica Sinica 1957,23,411.

[5]H. J. Dauben, Jr. , and S. H. -K. Jiang, The Attempted

Dehydrobromination of 2, 4-Dibromobicyclo (3,3,0 )-Octane, Acta

Chimica Sinica 1957,23,498.

[6]S. H. _K. Chiang, H. R. Davis, Fluorine-Containing Carbonyl

Sulfates and Their Production. U. S. Pat. 3214443(1965).

[7]Z. Ma, C. Chen, X. -K. Jiang, M. Ma, The Reaction of Bis (1,3-

Diphenyl-2-Imidazolidinylidene) with Several Perhalo Carboxylic

Acids and Perfluoropropene, Kexue Tongbao 1966,299.

[8]The Fluorocarbon Group, Shanghai Institute of Organic Chemistry,

Academia Sinica, Chemistry of Trifluorostyrenes and Their Dimers.

1. The Structures of the 1，2-Diphenylhexafluorocyclobutanes and

 

Their Pyrolysis, Acta Chimica Sinica 1976,34,17.

[9]The Fluorocarbon Group, Shanghai Institute of Organic Chemistry,

Academia Sinica, Structure-Property Relationships of Fluoroolefins.

I. The Polar and Solvent Effects in Free-Radical Additions, Scientia

Sinica 1977，20,116.

[10]X. -K. Jiang, G. -Z. Ji, C. -X. -Yu, A New Approach to the a ·

Scale, Acta Chimica Sinica 1984,42，599.

[11]X. -K. Jiang, Y. -Z. Hui, W. -Q. Fan, The Effect of Hydrophobic-

Lipophilic Interactions on Chemical Reactivity. 2. Solvent Effects on

the Aggregation and Self-Coiling of Long-Chain Molecules, Acta

Chimica Sinica 1984,42,1276.

[12]X. -K. Jiang, W. -Q. Fan, Y. -Z. Hui, The Effect of Hydrophobic-

Lipophilic Interactions on Chemical Reactivity. 4. A Case of 17-

Membered-Ring “Neighboring-Group” Participation： Compelling

Evidence for Self-Coiling, J. Am. Chem. Soc. 1984,106,7202.

[13]X. -K. Jiang, Y. -Z. Hui, W. -Q. Fan, The Effect of Hydrophobic-

Lipophilic Interactions on Chemical Reactivity. 1. New Evidence for

Intermolecular Aggregation and Self-Coiling, J. Am. Chem. Soc.

1984,106,3839.

 

[14]W. -Q. Fan, Xi-K. Jiang, The Effect of Hydrophobic-Lipophilic

Interactions on Chemical Reactivity. 6. The First Example of

Correlation of Hydrophobic-Lipophilic Substituent Constants with

Chemical Reactivity, J. Am. Chem. Soc. 1985,107,7680.

[15]C. -X. Zhao, X.-K. Jiang, G. -F. Chen, J. -Y. Lu, X. -S. Wang,

Y. -L. Qu, A Novel Technique for the Generation of Bis

(polyfluoroalkyl) and Polyfluoroalkyl Nitroalkyl Nitroxides. ESR

Verification of Mechanistic Propositions for the Reactions between

Polyfluorodiacyl Peroxides and Carbanions Derived from Secondary

Nitroalkanes, J. Am. Chem. Soc. 1986,108,3132.

[16]X.-K. Jiang, X.-Y. Li, C.-X. Zhao, G. -Z. Ji, Some Radical

Chemistry from Shanghai. Rev. Chem. Internat. 1986,7,195.

[17]X. -K. Jiang, G. -Z. Ji, C. -X. Yu, Structure-Property Relationships

of Fluoroolefins. 7. Substituent Effects on the Kinetic Parameters of

the Thermal Dimerization of Trifluorostyrenes, Acta Chimica Sinica

1986,44,72.

 

[18]X. -K. Jiang, Y. -Z. Hui, Z. -X. Fei, The Effect of Hydrophobic-

Lipophilic Interactions on Chemical Reactivity. 8. Large-Ring

Intramolecular Excimer Formation Brought About by Hydrophobic

Forces, J. Am. Chem. Soc. 1987,109,5862.

[19]G.-Z. Ji, Y. -Q. Shi, X. -K. Jiang, Extra Polar Interactions in the

Transition States of the Cross Cycloadditions of Differently

Substituted Trifluorostyrenes. 1. Kinetics of the Cycloadditions of 4-

Methoxy- and 4-Trifluoromethyl-trifluorostyrenes. Acta Chimica

Sinica 1988,46,1139.

[20]X. -K. Jiang, X. -Y. Li, B.-Z. Huang, The Effect of Hydorphobic-

Lipophilic Interactions on Chemical Reactivity. 11. The Dependence

of the Wrapping Capability of Sodium Carboxymethylamylose on Its

Degree of Substitution, J. Phy. Org. Chem. 1988,1,133.

[21]X. -K. Jiang, X. -Y. Li, B. -Z. Huang, The Effect of Hydrophobic-

Lipophilic Interactions on Chemical Reactivity. 12. Mechanistic

Investigations of NaCMA-Catalyzed Hydrolysis of Esters. What is

the Catalyzing Group? J. Phy. Org. Chem. 1988,1，143.

[22]X. -K. Jiang, Y. -Z. Hui, Z. -X. Fei, The Effect of Hydropobic-

Lipophilic Interactions on Chemical Reactivity. 14. A Successful

Applicaiton of the Concept of Making Use of the Hydrophobic Force

to Prepare Large-Ring Compounds, J. Chem. Soc. Chem. Commun.

1988,689； B. K. Carpenter, CHEMTRACTS - Org. Chem. 1988,1，

 

322.

[23]X. -K. Jiang, Hydrophobic-Lipophilic Interactions. Aggregation and

Self-Coiling of Organic Molecules, Acc. Chem. Res. 1988,21,362.

[24]X. -K. Jiang, X. -Y. Li, K. -Y. Wang, Reversal of the Nature of

Substituent Effect by Changing the Number of the α-Substituent.

Relative Ease of Formation of the Three α-Fluoromethyl Radicals, J.

Org. Chem. 1989，54，5648.

[25]G. -Z. Ji, X.-K. Jiang, Y.-H. Zhang, S.-G. Yuan, C.-X. Yu, Y.

-Q. Shi, X. -L. Zhang, W. -T. Shi, The Spin Delocalization

Substituent Parameter σ〓：5 Correlation Analysis of 〓F Chemical

Shifts of Substituted Trifluorostyrenes. The Unresolved Polar

Substituent Parameter σ〓，J. Phy. Org. Chem. 1990,3,643.

[26]X.-K. Jiang, Polyfluorinated Nitroxides, Pure Appl. Chem. 1990,

62,189.

[27]X.-K. Jiang, C. -X. Zhao, Y. -F. Gong, Reactivity and Reaction

Patterns of Alkyl Alkoxybenzene Radical Cations. Mechanistic

Pathways of the Reactions between 2，5-Di-tert-Butyl-1, 4-

dimethoxybenzene and Perfluorodiacyl Peroxides, J. Phy. Org.

Chem. 1991,4,1.

[28]X.-K. Jiang, G. -Z. Ji, J. -S. Wang, Electrostatically Stabilized

Aggregate (ESAg). I. Evidence Derived from the Coaggregating

Behavior of an Anionic Kinetic Probe (P16〓) with Surfactants,

Chinese Chem. Lett. 1991,2,813.

[29]X. -K. Jiang, G. -Z. Ji, J. -S. Wang, Electrostatically Stabilized

Aggregate (ESAg). II. Evidence Derived from the Coaggregating

Behavior of a Cationic Kinetic Probe (P16〓) with Surfactants,

Chinese Chem. Lett. 1992,3,231.

[30]X. -K. Jiang, G. -Z. Ji, A Self-Consistent and Cross-Checked Scale of

Spin-Delocalization Substituent Constants, the σ〓 scale. J. Org.

Chem. 1992,57,6051.

[31]H.-X. Guo, S. -X. Sun, G.-Z. Ji, X. -K. Jiang, Single-Parameter

versus Dual-Parameter Correlation for Radical Reactions. A

Dichotomy of Mechanism for Tricholomethyl-bromo-addition

Reactions to Styrenes, J. Chem. Res. S 1993,166; J. Chem. Res.

M 1993,1123.

[32]X. -K. Jiang, J. -S. Wang, Electrostatically Stabilized Aggregate

(ESAg). III. Evidence Derived from the Coaggregating Behavior of

Fluorescence Probes (FP) with Ionic Surfactants, Chinese J. Chem.

1993,11,472.

 

[33]X. -K. Jiang, G. -Z. Ji, J. -T. Zhang, Effective Neutral

Deaggregators, Langmuir，1994,10,122.

[34]X. -K. Jiang, New Concepts for Studying and Understanding the

Aggregation, Coaggregation, Deaggregation and Self-Coiling of

Organic Molecules. Why Are Cholesterols and Triglycerides Culprits

of Arteriosclerosis? Pure Appl. Chem. 1994,66,1621.

[35]J. -T. Zhang, J. Nie, G. -Z. Ji, X. -K. Jiang, Methodology for

Measuring the Critical Aggregate Concentration of Nonprobe

Molecules, Langmuir, 1994,10,2814.

[36]X. -K. Jiang, W. -Z. Liu, S. -H. Wu, Single-Parameter versus Dual-

Parameter Correlation for Radical Reactions. The Addition of

Bromine Atoms to α-Methylstyrenes, J. Phy. Org. Chem. 1994,

7,96.

[37]X. -K. Jiang, G. -Z. Ji, Z. -R. Wang, The Spin-Delocalization

Substituent Parameter σ：9. Cyclodimerization Rates of p-

Methylsulfinyl and p-Methylsulfonyl α,β，β-Trifluorostyrenes, J. 

Fluorine Chem. 1994,66,187.

[38]X.-K Jiang, W. -Z. Liu, S. -H. Wu, Can the Spin-Delocalization

Effect Express Itself at the Transition State of the Hydrogen-Atom

Abstraction Reaction? Correlation Analysis of Relative Rates

Measured by a Rigorous Methodology for Eleven p-Y-Substituted

Isopropylbenzenes, Tetrahedron，1994,50,7503.

[39]X. -K. Jiang, G. -Z. Ji, B. Tu, X. -Y. Zhang, J. -L. Shi, X. Chen,

Shape and Aggregating Tendency. The Aggregating Behavior of

Eight Esters of Eight-Carbon Carboxylic Acids, J. Am. Chem.

Soc. , 1995,117,12679.

[40]X. -K. Jiang, G. -Z. Ji, Z. -R. Wang, First Successful Correlation of

the UV Spectra of Three Kinds of Styrenes with Spin-Delocalization

Substituent Constants σ· J. Phy. Org. Chem. 1995,8,143.

[41]X. -K. Jiang, G. -Z. Ji, Z. -R. Wang, R. -Y. Xie, Successful Application

of the Spin-Delocalization Substituent Constants σ· to the Correlation of

the UV Spetra of Some Model Compounds with para-Y-Substituted

Phenyl Groups, J. Phy. Org. Chem. 1995,8,781.

[42]X. -K. Jiang, G. -Z. Ji, R. -Y. Xie, In Search of the Spin-

Delocalization Effect from the Correlation Analysis of Relative Rates

of the Trichloromethyl-Bromo-Addition Reactions to Fourteen p-Y-

Substituted Phenylacetylenes, Tetrahedron 1996,52,3017.

[43]X.-K. Jiang, G.-Z. Ji, R.-Y. Xie, The Electrophilic

Trifluoromethyl Radical, Application of the Dual-parameter Equation

to the Correlation Analysis of Relative Rates of the

Trifluoromethylbromo Addition Reactions to 14 p-Y-substituted

phenylacetylenes, J. Fluorine Chem. 1996,79,133.

[44]X. -K. Jiang, J.-L. Shi, X. Chen, Aggregating Tendencies of Some

Phosphonates and Phosphinates, Langmuir 1996,12,3881.

[45]J. -L. Shi, X. C.，X. -K. Jiang, Hydrophobic Acceleration of

Electron Transfer Processes, J. Org. Chem. , 1996,61 ,4698.

[46]蒋锡夔，关于科学的思想方法的一些认识，中国科学院院刊，1997，

1,52.

 

[47]X. -K. Jiang, F. -X. Ding, Y. -H. Zhang, The Nucleophilic Silyl

Radical： Dual-Parameter Correlation Analysis of the Relative Rates of

Bromine-Atom Abstraction Reactions as Measured by a Rigorous

Methodology, Tetrahedron 1997,53，8479.

[48]X. -K. Jiang, Establishment and Successful Application of the

σ〓 Scale of Spin-Delocalization Substiuent Constants, Acc. Chem. Res.

1997,30,283.

 

[49]J. -L. Shi, X. -W. Jiang, H. Zeng, X. -K. Jiang, Aggregating

Tendencies of Some Alkyl Sulfonates, Langmuir 1997,13,2480.

[50]Y. Zhu, X. -Y. Zhang, H. Zeng, X. -K. Jiang, Nature of the

Alternate -CF〓CH〓- Chain： A Study Based on the Measurement and

Comparison of the CAgC’s of Aggregators with Alternate Chain and

with Hydrocarbon Chain, Langmuir 1997,13,3603.

[51]B. Tu, G. -Z. Ji, X. -K. Jiang, Two Types of Salt Effects： for Ag

(Aggregate) Formation and for ESAg (Electrostatically Stabilized

Aggregate) Formation, Langmuir 1997,13,4234.

[52]H. -Y. He, X. -K. Jiang, Dual-parameter correlation analysis of UV

spectral data for 1-methyl-2-formyl-5-Y-substituted pyrroles and their

hydrazones. First observation of a dominant polar effect, J. Phys.

Org, Chem. 1999,12,392.

著作

[1]蒋锡夔，孙思汛.有机氟化物反应中某些有用的规律性概念及非自由

基型反应的反应规律.见:黄维垣主编.中国有机氟化学研究.上海:上

海科学技术出版社，1996。X. -K. Jiang, S. -X. Sun, Useful Basic

Concepts in Fluoroorganic Chemistry. Generalizations on the Non-

Radical Reactions of the C-F Bond, in “Fluoroorganic Chemistry in

China”，Ed. Wei-Yuan Huang, Shanghai Sciences and Technology

Press ： Shanghai, 1996, Chapter 1.

[2]蒋锡夔、张劲涛.有机分子的簇集和自卷.上海：上海科学技术出版社，

1996。 X. -K. Jiang, J. -T. Zhang, Aggregation and Self-Coiling of

 

Organic Molecules, Shanghai Sciences and Technology Press：

Shanghai, 1996.